Thermotropic liquid crystals from biomacromolecules.

نویسندگان

  • Kai Liu
  • Dong Chen
  • Alessio Marcozzi
  • Lifei Zheng
  • Juanjuan Su
  • Diego Pesce
  • Wojciech Zajaczkowski
  • Anke Kolbe
  • Wojciech Pisula
  • Klaus Müllen
  • Noel A Clark
  • Andreas Herrmann
چکیده

Complexation of biomacromolecules (e.g., nucleic acids, proteins, or viruses) with surfactants containing flexible alkyl tails, followed by dehydration, is shown to be a simple generic method for the production of thermotropic liquid crystals. The anhydrous smectic phases that result exhibit biomacromolecular sublayers intercalated between aliphatic hydrocarbon sublayers at or near room temperature. Both this and low transition temperatures to other phases enable the study and application of thermotropic liquid crystal phase behavior without thermal degradation of the biomolecular components.

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عنوان ژورنال:
  • Proceedings of the National Academy of Sciences of the United States of America

دوره 111 52  شماره 

صفحات  -

تاریخ انتشار 2014